Magnesium-catalysed hydroboration of isonitriles.
نویسندگان
چکیده
A β-diketiminato magnesium alkyl complex is shown to be an effective pre-catalyst for the first reported catalytic hydroboration of organic isonitriles, RNC, with HBpin. The reaction proceeds under mild conditions when R = alkyl and provides access to the corresponding 1,2-diborylated amine products.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 77 شماره
صفحات -
تاریخ انتشار 2015